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Visible-Light Photocatalyzed Deoxygenation of N-Heterocyclic N-Oxides
A scalable and operationally simple method is described that allows for the chemoselective deoxygenation of a wide range of N-heterocyclic N-oxides (a total of 36 examples). This visible-light-induced protocol features the use of only commercially available reagents, room-temperature conditions, and unprecedented chemoselective removal of the oxygen atom in a quinoline N-oxide in the presence of a pyridine N-oxide in the same molecule through the judicious selection of a photocatalyst.
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Phthalazine – Wikipedia,
Phthalazine | C8H6N237 – PubChem