Related Products of 253-52-1, The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.253-52-1, Name is Phthalazine, molecular formula is C8H6N2. In a Article£¬once mentioned of 253-52-1
Copper(I) cyanide networks: Synthesis, luminescence behavior and thermal analysis. Part 1. Diimine ligands
Metal-organic networks of CuCN with diimines (L) = pyrazine (Pyz), 2-aminopyrazine (PyzNH2), quinoxaline (Qox), phenazine (Phz), 4,4?-bipyridyl (Bpy), pyrimidine (Pym), 2-aminopyrimidine (PymNH 2), 2,4-diaminopyrimidine (Pym(NH2)2), 2,4,6-triaminopyrimidine (Pym(NH2)3), quinazoline (Qnz), pyridazine (Pdz), and phthalazine (Ptz) were studied. Open reflux reactions produced complexes (CuCN)2(L) for L = Qox, Phz, Bpy, PymNH 2, Pym(NH2)2, Qnz, and Pdz and (CuCN) 3(L) complexes for L = Pyz, PyzNH2, Qox, Bpy, Pym(NH 2)3,l and Pdz. Also produced were (CuCN) 3(Pyz)2, (CuCN)(PyZNH2), (CuCN) 7(Pym)2, (CuCN)5(Qnz) 2 and (CuCN)5(Ptz)2. X-ray structures are presented for (CuCN)2(Pdz), (CuCN)2(PymNH2), and (CuCN) 7(Pym)2. Hydrothermal reactions yielded additional X-ray structures of (CuCN)2(PyzNH2), (CuCN) 3(Pym(NH2)2), (CuCN)4(Qnz), a second (CuCN)2(Pdz) phase, (CuCN)5(Pdz)2, (CuCN) 2(Ptz), and (CuCN)7(Ptz)2. Structural trends, including cuprophilic interactions and cyano-bridged Cu2(CN) 2 dimer formation, are discussed. Particularly short Cu…Cu interactions are noted for the novel 4- and 5-coordinate Cu2-(CN) 2 dimers. Thermal analyses show that most of the complexes decompose with loss of L around 160-180C. Luminescence behavior is relatively weak in the products.
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Reference£º
Phthalazine – Wikipedia,
Phthalazine | C8H6N450 – PubChem