Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 619-67-0, Name is 4-Hydrazinylbenzoic acid, molecular formula is C7H8N2O2. In an article, author is Szavuly, Miklos,once mentioned of 619-67-0, SDS of cas: 619-67-0.
Catalytic oxidation of alcohols and sulfides with hydrogen peroxide using isoindoline and phthalazine-based diiron complexes
A series of diiron(III) complexes of 1,3-bis(2′-arylimino)isoindoline, [(Fe(L)Cl)(2)O] and 1,4-di-(2′-aryl)aminophthalazine, [Fe-2(mu-OMe)(2)(H2L)Cl-4], including new structurally characterized ligands, 1,4-di-(4′-methyl-2′-thiazolyl)aminophthalazine and 1,4-di-(2′-benzthiazolyl)-aminophthalazine, have been characterized, and used as catalysts for the oxidation of para-substituted phenyl methyl sulfides and benzyl alcohols. Hammett correlations and kinetic isotope effect experiments support the involvement of electrophilic metal-based oxidants. In case of [(Fe(L-1,L-2)Cl)(2)O] catalysts, direct correlation has been found between the oxidative and catalase-like activity. (C) 2014 Elsevier B.V. All rights reserved.
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Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem