Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Kokunov, Yu. V., once mentioned the application of 4474-86-6, Name is N-Cbz-D-Asparagine, molecular formula is C12H14N2O5, molecular weight is 266.25, MDL number is MFCD00065696, category is phthalazine. Now introduce a scientific discovery about this category, Name: N-Cbz-D-Asparagine.
Binuclear complex of silver(I) perrhenate with phthalazine: Synthesis, crystal structure, and luminescence properties
Silver compound Ag-2(Phtz)(4)](ReO4)(2) (I) (Phtz is phthalazine, C8H6N2) is synthesized, and its crystal structure is determined. The crystals are triclinic: space group , a = 9.651(2), b = 9.655(2), c = 10.884(2) , alpha = 115.752(2)A degrees, beta = 94.582(2)A degrees, gamma = 106.000(2)A degrees, V = 854.3(2) (3), Z = 1, rho(calcd) = 2.404 g/cm(3). The Ag atom forms a triangular coordination mode (Ag(1)-N(11) 2.34(2), Ag(1)-N(12AEuro) 2.24(2), and Ag(1)-N(21) 2.28(1) ) by the nitrogen atoms of one monodentate and two bridging phthalazine molecules. Their interaction results in the formation of an almost planar centrosymmetric binuclear cationic complex [Ag-2(Phtz)(4)](2+) (Ag(1)a <-Ag(1A) 3.452(7) ). The oxygen atoms of the ReO (4) (-) anion are randomly disordered over three positions each. The luminescence spectrum contains an emission band in the green region. Do you like my blog? If you like, you can also browse other articles about this kind. Thanks for taking the time to read the blog about 4474-86-6, Name: N-Cbz-D-Asparagine.
Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem