Application of 14348-75-5, Enzymes are biological catalysts that produce large increases in reaction rates and tend to be specific for certain reactants and products. 14348-75-5, Name is 2,7-Dibromo-9H-fluoren-9-one, SMILES is C3=C2C1=C(C=C(Br)C=C1)C(C2=CC(=C3)Br)=O, belongs to phthalazine compound. In a article, author is Brachet, Etienne, introduce new discover of the category.
Visible light amination/Smiles cascade: access to phthalazine derivatives
We report the synthesis of various phthalazines via a new cascade reaction, initiated by visible light photocatalysis, involving a radical hydroamination reaction followed by a radical Smiles rearrangement. Phthalazine derivatives are obtained in high yields and from a broad scope readily accessible orthoalkynylsulfonohydrazone precursors. The mild photoredox conditions ensure an excellent functional group tolerance. Application of this strategy to a one-pot protocol starting from the corresponding carbonyl compounds, and subsequent functionalization allow the rapid synthesis of structurally diverse structures.
Application of 14348-75-5, Each elementary reaction can be described in terms of its molecularity, the number of molecules that collide in that step. The slowest step in a reaction mechanism is the rate-determining step.you can also check out more blogs about 14348-75-5.
Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem