Chemistry involves the study of all things chemical – chemical processes, chemical compositions and chemical manipulation – in order to better understand the way in which materials are structured, how they change and how they react in certain situations. , Recommanded Product: Phenethyl acetate, 103-45-7, Name is Phenethyl acetate, molecular formula is C10H12O2, belongs to phthalazine compound. In a document, author is De Abreu, Maxime, introduce the new discover.
Phosphoramidates are for the first time presented as efficient N-Centered Radical (NCR) precursors under visible-light irradiation. More precisely among this class of phosphorus-derived compounds, we studied the radical reactivity of phosphonohydrazones, under mild reaction conditions, which allowed the synthesis of a wide and diversified library of the scarcely reported phthalazine scaffold. Mechanistic investigations confirmed the formation of a NCR from these brand-new phosphonohydrazones (derivatived from phosphoramidates), which were further engaged in an intramolecular 6-exo-dig cyclization to provide phthalazines. Compared to other pre-activated moieties, the phosphoramidate group is self-immolative, thus enhancing its attractiveness for the C-N bond formation.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 103-45-7 help many people in the next few years. Recommanded Product: Phenethyl acetate.
Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem