Safety of 4-(Methylamino)-3-nitrobenzoic acid, Chemistry graduates have much scope to use their knowledge in a range of research sectors, including roles within chemical engineering, chemical and related industries, healthcare and more. 41263-74-5, Name is 4-(Methylamino)-3-nitrobenzoic acid, SMILES is O=C(O)C1=CC=C(NC)C([N+]([O-])=O)=C1, belongs to phthalazine compound. In a article, author is Arian, Fatemeh, introduce new discover of the category.
Three novel sultone based Bronsted acidic ionic liquids are introduced. These ionic liquids were prepared in three similar two-steps reactions. The ring opening of 1,4-butane sultone was performed using 1,4-dimethyl piperazine or 1,10-phenantroline as nitrogen nucleophile sources to obtain zwitterions and then followed by acidification by treatment with perchloric acid to give the introduced ionic liquids. FTIR, (HNMR)-H-1, C-13-NMR, TGA and CHNS analysis techniques were used for the characterization of these ionic liquids. These ionic liquids are completely water soluble and have good thermal stability. Their catalytic efficiency was checked for the preparation of polycyclic 2H-indazolo[2,1-b]phthalazine-trione compounds. Small amount (3-7 mmol%) of the prepared acidic ionic liquid catalysts is required and targeted products are obtained in short times (6-25 min) at high yields (86-96%). Moreover, the introduced acidic ionic liquids are completely green, environmental benign and task specific and simply recoverable up to six consecutive runs without significant decrease in their catalytic. (C) 2020 Elsevier B.V. All rights reserved.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 41263-74-5, in my other articles. Safety of 4-(Methylamino)-3-nitrobenzoic acid.
Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem