An article Ruthenium-Catalyzed Regioselective Olefin Migration of Dihydropyran Acetals: A De Novo Strategy toward beta-2,6-Dideoxypyranoglycosides WOS:000526331100013 published article about STEREOSELECTIVE-SYNTHESIS; ASYMMETRIC-SYNTHESIS; GLYCOSYLATION; 2-DEOXY-BETA-GLYCOSIDES; DIGITOXIN; SUGARS; ANTIBIOTICS; DONORS in [Seo, Kyeongdeok; Rhee, Young Ho] POSTECH, Dept Chem, Pohang 37673, South Korea in 2020.0, Cited 47.0. Recommanded Product: 4-Nitrobenzoic acid. The Name is 4-Nitrobenzoic acid. Through research, I have a further understanding and discovery of 62-23-7
Here, we report a de novo synthetic strategy toward beta-2,6-dideoxypyranoglycosides. The key event is the ruthenium-catalyzed regioselective olefin migration of dihydropyran allylic acetals to homoallylic acetals. In combination with other metal-catalyzed reactions, this new protocol led to the synthesis of beta-2,6-dideoxypyranoglycosides in a highly efficient manner. Using this sequential metal catalysis, various mono-, di-, and trisaccharide forms of beta-2,6-dideoxypyranoglycosides were prepared.
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Reference:
Phthalazine – Wikipedia,
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