In 2020.0 ADV SYNTH CATAL published article about FORMING REDUCTIVE ELIMINATION; DIRECT ORTHO-ARYLATION; METAL-METAL BONDS; SUPPORTED PRECATALYSTS; OXIDATIVE ADDITION; PD-IV; PALLADIUM; COMPLEXES; HALIDES; ACTIVATION in [Li, Li; Song, Feifei; Wu, Yun-Dong; Zhang, Xinhao; Chen, Jiean; Huang, Yong] Peking Univ, Shenzhen Grad Sch, State Key Lab Chem Oncogen, Key Lab Chem Genom, Shenzhen 518055, Guangdong, Peoples R China; [Zhong, Xiumei; Zhang, Xinhao; Chen, Jiean] Shenzhen Bay Lab, Shenzhen 518055, Guangdong, Peoples R China; [Huang, Yong] Hong Kong Univ Sci Technol, Dept Chem, Kowloon, Clear Water Bay, Hong Kong, Peoples R China in 2020.0, Cited 90.0. The Name is 4-Nitrobenzoic acid. Through research, I have a further understanding and discovery of 62-23-7. Computed Properties of C7H5NO4
Palladium-catalyzed cross-coupling reactions between carboxylic acids and aryl halides have several possible competitive pathways. Decarboxylative C-C bond coupling and C-H arylation are well established in the literature. However, direct C-O bond coupling between carboxylic acids and aryl halides has received little success. In this report, we describe a protocol for exclusive C-O bond formation, enabled by a bidentate N,N-ligand such as 1,10-phenanthroline. The reaction is general for a broad range of carboxylic acids and iodoarenes. Experimental evidence and computational results suggest a high energy barrier for the alternative pathway of decarboxylative carbon-carbon bond coupling.
Computed Properties of C7H5NO4. Bye, fridends, I hope you can learn more about C7H5NO4, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem