Recently I am researching about ORGANIC-COMPOUNDS; ESTERIFICATION; ALCOHOLS; HALOGENATION; POLYMERS; WATER; ACIDS, Saw an article supported by the Slovenian Research AgencySlovenian Research Agency – Slovenia [P1-0134, ARRS-SP-2990/17]; Serbian Ministry of Education, Science and Technological Development [173052]. Published in MDPI in BASEL ,Authors: Cebular, K; Bozic, BD; Stavber, S. The CAS is 62-23-7. Through research, I have a further understanding and discovery of 4-Nitrobenzoic acid. Application In Synthesis of 4-Nitrobenzoic acid
Activation of carbonyl moiety is one of the most rudimentary approaches in organic synthesis and is crucial for a plethora of industrial-scale condensation reactions. In esterification and aldol condensation, which represent two of the most important reactions, the susceptibility of the carbonyl group to nucleophile attack allows the construction of a variety of useful organic compounds. In this context, there is a constant need for development of and improvement in the methods for addition-elimination reactions via activation of carbonyl functionality. In this paper, an advanced methodology for the direct esterification of carboxylic acids and alcohols, and for aldol condensation of aldehydes using widely available, inexpensive, and metal-free 1,3-dibromo-5,5-dimethylhydantoin under neat reaction conditions is reported. The method is air- and moisture-tolerant, allowing simple synthetic and isolation procedures for both reactions presented in this paper. The reaction pathway for esterification is proposed and a scale-up of certain industrially important derivatives is performed.
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Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem