Month: November 2021

An article Effect of Fe, Co and Ni promoters on MoS2 based catalysts for chemoselective hydrogenation of nitroarenes WOS:000521329900007 published article about SELECTIVE HYDROGENATION; EFFICIENT PHOTOCATALYST; NITROBENZENE REDUCTION; CARBON NANOTUBES; ACTIVE-SITES; SURFACE; NITROAROMATICS; ACTIVATION; PARTICLES; MECHANISM in [Han, Wenpeng; Li, Xuekuan; Ma, Ben; Du, Mingxian; Zhou, Ligong; Yang, Ying; Zhang, Ye; Ge, Hui] Chinese Acad Sci, Inst Coal Chem, Taiyuan 030001, Peoples R China; [Han, Wenpeng] Univ Chinese Acad Sci, Beijing 100049, Peoples R China; [Wang, Shanmin] Southern Univ Sci & Technol, Dept Phys, Shenzhen 518055, Guangdong, Peoples R China in 2020, Cited 56. The Name is 4-Nitrobenzoic acid. Through research, I have a further understanding and discovery of 62-23-7. Recommanded Product: 4-Nitrobenzoic acid

The effect of Fe, Co and Ni promoters on supported MoS2 catalysts for hydrogenation of nitroarenes were systematically investigated via experiment, characterization and DFT calculation. It was found that the addition of promoters remarkably improved the reaction activity in a sequence of Ni > Co > Fe > Mo. Meanwhile Ni promoted catalyst with the best performance showed good recyclability and chemoselectivity for a wide substrate scope. The characterization results revealed that the addition of promoters decreased the interaction between Mo and support and facilitated the reductive sulfidation of Mo species to produce more coordinated unsaturated sites (CUS). DFT calculations showed that the addition of promoters increased the formation of CUS, and enhanced the adsorption of hydrogen. The influence degree of promoters followed the sequence Ni > Co > Fe > Mo, which was consistent with those of the activities. Nitrobenzene hydrogenation and hydrogen activation occurred at the S and Mo edge, respectively. The adsorbed hydrogen diffused from the Mo edge to the S edge to participate in the hydrogenation reaction. Mechanism investigation showed that the main reason for increased activity by the addition of promoters was the increase of amounts of CUS and the secondary reason was the augmentation of intrinsic activity of CUS. The present studies give a new understanding for promoter modified MoS2 catalysts applied for hydrogenation of nitroarenes.

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Phthalazine – Wikipedia,
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In 2020.0 APPL CLAY SCI published article about SELECTIVE OXIDATION; HIGHLY EFFICIENT; SOLVENT-FREE; WATER; HYDROGEN; MNO2; NANOPARTICLES; DEGRADATION; ALDEHYDES; CATALYST in [Pazoki, Farzane; Shamsayei, Maryam; Bagheri, Sepideh; Yazdani, Elahe; Heydari, Akbar] Tarbiat Modares Univ, Fac Sci, Dept Chem, Tehran 1411713116, Iran in 2020.0, Cited 38.0. The Name is 4-Nitrobenzoic acid. Through research, I have a further understanding and discovery of 62-23-7. Product Details of 62-23-7

In the present work, MnO2@Mg-Al layered double hydroxide (LDH) has been prepared via a simple coprecipitation method and characterized successfully. Two products are formed from benzyl alcohol oxidation over MnO2@Mg-Al layered double hydroxide (LDH): benzaldehyde and benzoic acid. This oxidation was carried out with three different parameters: oxidant, solvent, and temperature. In addition, MnO2@Mg-Al LDHs could be easily recovered and reused for five times without any loss of activity.

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Reference:
Phthalazine – Wikipedia,
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Recently I am researching about IN-SITU GENERATION; DIFLUOROMETHYL DIAZOMETHANE; TRIFLUOROMETHYL DIAZOMETHANE; 3+2 CYCLOADDITION; CARBOXYLIC-ACIDS; ETHOSUXIMIDE; DERIVATIVES; FLUORINE; CF3CHN2; 2,2,2-TRIFLUORODIAZOETHANE, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21502076]; Natural Science Foundation of Jiangxi provinceNatural Science Foundation of Jiangxi Province [20161BAB213068]; Outstanding Young Talents Scheme of Jiangxi Province [20171BCB23039]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Gao, Y; Peng, SQ; Liu, DY; Rui, PX; Hu, XG. The CAS is 62-23-7. Through research, I have a further understanding and discovery of 4-Nitrobenzoic acid. Safety of 4-Nitrobenzoic acid

A general and efficient method for the synthesis N-difluoroethyl imides has been developed. This copper-catalyzed four-component reaction proceeds via in-situ generated difluorodiazomethane, which does not require prior formation and transferring. The reaction is scalable, tolerant toward a range of functional groups, and also suitable for the late-stage functionalization of drugs and drug-like molecules.

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Reference:
Phthalazine – Wikipedia,
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In 2019 MOL CATAL published article about OXIDE GAS SENSORS; SOLVENT-FREE; ENERGY-CONVERSION; O-SILYLATION; SELECTIVE SILYLATION; METAL-OXIDES; ALCOHOLS; HMDS; PHENOLS; MILD in [Anbu, Nagaraj; Vijayan, Chellappa; Dhakshinamoorthy, Amarajothi] Madurai Kamaraj Univ, Sch Chem, Madurai 625021, Tamil Nadu, India in 2019, Cited 51. The Name is 4-Nitrobenzoic acid. Through research, I have a further understanding and discovery of 62-23-7. Recommanded Product: 62-23-7

In this study, a mild and efficient method is developed for the silylation of diverse functional groups using CeO2 nanoparticles (n-CeO2) as solid catalysts with hexamethyldisilazane (HMDS) as silylating agent at room temperature. Alcohols, phenols and acids are silylated to their respective silyl derivatives with faster reaction rate while amines and thiols required relatively longer reaction time. Moreover, the solid catalyst is easily be separated from the reaction mixture and recycled more than five times without any obvious decay in its activity. Powder X-ray diffraction (XRD), transmission electron microscope (TEM), UV-vis diffuse reflectance spectra (UV-DRS) and Raman analyses revealed identical structural integrity, particle size, absorption edge and valence state for the reused solid compared to the fresh solid catalyst.

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Reference:
Phthalazine – Wikipedia,
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I found the field of Chemistry very interesting. Saw the article Amide Synthesis through the In Situ Generation of Chloro- and Imido-Phosphonium Salts published in 2020. HPLC of Formula: C7H5NO4, Reprint Addresses Laulhe, S (corresponding author), Indiana Univ Purdue Univ Indianapolis IUPUI, Dept Chem & Chem Biol, Indianapolis, IN 46202 USA.. The CAS is 62-23-7. Through research, I have a further understanding and discovery of 4-Nitrobenzoic acid

We describe a methodology for the amidation of carboxylic acids by generating phosphonium salts in situ from N-chlorophthalimide and triphenylphosphine. Aliphatic, benzylic, and aromatic carboxylic acids can be transformed into their amide counter parts using primary and secondary amines. This functional group interconversion is achieved at room temperature in good to excellent yields. Mechanistic work shows the in situ formation of chloro- and imido-phosphonium salts that react as activating agents for carboxylic acids and generate an acyloxyphosphonium species.

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Reference:
Phthalazine – Wikipedia,
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Computed Properties of C7H5NO4. In 2019 EUR J MED CHEM published article about MULTIDRUG-RESISTANT; ANTIMYCOBACTERIAL ACTIVITY; PHARMACOLOGICAL EVALUATION; ANTITUBERCULOSIS ACTIVITY; ANTICANCER ACTIVITY; DERIVATIVES; TUBERCULOSIS; THIADIAZOLES; CYTOTOXICITY; BEDAQUILINE in [Patel, Harun; Jadhav, Harsha; Ansari, Iqrar; Pawara, Rahul; Surana, Sanjay] RC Patel Inst Pharmaceut Educ & Res, Dept Pharmaceut Chem, Shirpur, India in 2019, Cited 33. The Name is 4-Nitrobenzoic acid. Through research, I have a further understanding and discovery of 62-23-7.

In the present study, a series of substituted 1,3,4-thiadiazole derivatives 4(a-o), 5(a-m) and 6(a-j) were synthesized and characterized by IR, H-1 NMR, C-13 NMR and mass spectroscopic technique. The synthesized compounds were evaluated for their in vitro anti-mycobacterial activity against the Mycobacterium tuberculosis H37Rv and resistance MDR-TB strain. Among the compounds tested N-(5-(4-nitrophenyl)-1,3,4-thiadiazol-2-yl)furan-2-carboxamide (4h) showed significant inhibitory activity with MIC of 9.87 mu M (H37Rv strain) and 9.87 mu M (MDR-TB strain) compared to isoniazide (MIC of 3.64 mu M (H37Rv) and >200 mu M (MDR-TB strain)] and rifampin [MIC of 0.152 mu M (H37Rv) and 128 mu M (MDR-TB strain)]. In addition, these compounds have also been assessed for their cyto-toxicity to a mammalian Vero cell line using the MTT assay. The result shows that these compounds exhibit anti-tubercular activity at non-cytototoxic concentrations. (C) 2019 Elsevier Masson SAS. All rights reserved.

Welcome to talk about 62-23-7, If you have any questions, you can contact Patel, H; Jadhav, H; Ansari, I; Pawara, R; Surana, S or send Email.. Computed Properties of C7H5NO4

Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem

SDS of cas: 62-23-7. Sadjadi, S; Malmir, M; Pourmohammad, N; Ahmadi, S; Heravi, MM in [Sadjadi, Samahe] Iran Polymer & Petrochem Inst, Fac Petrochem, Gas Convers Dept, POB 14975-112, Tehran, Iran; [Malmir, Masoumeh; Pourmohammad, Nargess; Heravi, Majid M.] Alzahra Univ, Sch Sci, Dept Chem, POB 1993891176, Tehran, Iran; [Ahmadi, Shervin] Iran Polymer & Petrochem Inst, Dept Polymer Proc, Tehran, Iran published Combination of polymer and halloysite chemistry for development of a novel catalytic hybrid system in 2019.0, Cited 61.0. The Name is 4-Nitrobenzoic acid. Through research, I have a further understanding and discovery of 62-23-7.

A covalent hybrid of halloysite-poly(methyl methacrylate-co-maleic anhydride) was prepared and applied for the immobilization of Pd nanoparticles. The hybrid system, Pd@Hal-Gua-Poly, was then characterized via TEM, TGA, ICP, BET, FTIR and XRD and successfully used as a heterogeneous catalyst for promoting two main Pd-catalyzed reactions, i.e. hydrogenation of nitro-arenes and Suzuki coupling reaction under mild and eco-friendly conditions. The study of recyclability of the catalyst confirmed high recyclability and low Pd leaching of Pd@Hal-Gua-Poly. Moreover, the hot-filtration test showed the heterogeneous nature of the catalysts. Notably, the comparison of the activity of the catalyst with that of Pd@Hal and Pd@Poly confirmed the superior catalytic activity of the former, indicating that the hybridization of Hal and Poly could lead to the improvement of the catalytic activity. [GRAPHICS] .

SDS of cas: 62-23-7. Welcome to talk about 62-23-7, If you have any questions, you can contact Sadjadi, S; Malmir, M; Pourmohammad, N; Ahmadi, S; Heravi, MM or send Email.

Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem

An article Ruthenium-Catalyzed Regioselective Direct Ortho-Acyloxylation of Azoarenes with Carboxylic Acids via C-H Bond Activation WOS:000458273900018 published article about AROMATIC AZO-COMPOUNDS; DECARBOXYLATIVE ORTHO-ACYLATION; C(SP(2))-H BONDS; DIRECT ACCESS; AZOBENZENES; ACETOXYLATION; HYDROXYLATION; OXYGENATIONS; ARYLATION; ANILINES in [Kianmehr, Ebrahim; Nasab, Sepideh Bahrami] Univ Tehran, Sch Chem, Coll Sci, Tehran, Iran in 2019, Cited 73. Application In Synthesis of 4-Nitrobenzoic acid. The Name is 4-Nitrobenzoic acid. Through research, I have a further understanding and discovery of 62-23-7

A Ru-II-catalyzed highly regioselective C-H acyloxylation of azoarenes with inexpensive alkyl and aryl carboxylic acids as an acyloxylation agent is described. The reaction demonstrates a broad substrate scope and good functional group tolerance. This method provides a facile procedure to synthesize ortho-acyloxylated azoarene derivatives.

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Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem

Computed Properties of C7H5NO4. In 2020 APPL ORGANOMET CHEM published article about DIRECT AMIDE FORMATION; BOND FORMATION; CONDENSATION in [Wang, Hui; Dong, Wei; Hou, Zhipeng; Cheng, Lidan; Li, Xiufen; Huang, Longjiang] Qingdao Univ Sci & Technol, Coll Chem Engn, State Key Lab Base Ecochem Engn, Qingdao 266042, Peoples R China in 2020, Cited 40. The Name is 4-Nitrobenzoic acid. Through research, I have a further understanding and discovery of 62-23-7.

This paper described a mild and efficient direct amidation of non-activated carboxylic acid and amine derivatives catalyzed by TiCp2Cl2. Arylacetic acid derivatives reacted with different amines to afford the corresponding amides in good to excellent yield except of aniline. Aryl formic acids failed to react with aniline but smoothly reacted with aliphatic amines and benzylamine in moderate to good yield, fatty acids reacting with benzyl and aliphatic amines give amides in good to excellent yield. Chiral amino acids derivatives were transformed into amides without racemization in moderate yield. The possible mechanism of direct amidation catalyzed by TiCp2Cl2 was discussed. This catalytic method is very suitable for the amidation of low sterically hindered arylacetic acid, fatty acids with different low sterically hindered amines except aniline, as well as the amidation of aryl formic acid with benzyl and aliphatic amines.

Computed Properties of C7H5NO4. Welcome to talk about 62-23-7, If you have any questions, you can contact Wang, H; Dong, W; Hou, ZP; Cheng, LD; Li, XF; Huang, LJ or send Email.

Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem

I found the field of Chemistry very interesting. Saw the article A simple and efficient room temperature silylation of diverse functional groups with hexamethyldisilazane using CeO2 nanoparticles as solid catalysts published in 2019. Safety of 4-Nitrobenzoic acid, Reprint Addresses Dhakshinamoorthy, A (corresponding author), Madurai Kamaraj Univ, Sch Chem, Madurai 625021, Tamil Nadu, India.. The CAS is 62-23-7. Through research, I have a further understanding and discovery of 4-Nitrobenzoic acid

In this study, a mild and efficient method is developed for the silylation of diverse functional groups using CeO2 nanoparticles (n-CeO2) as solid catalysts with hexamethyldisilazane (HMDS) as silylating agent at room temperature. Alcohols, phenols and acids are silylated to their respective silyl derivatives with faster reaction rate while amines and thiols required relatively longer reaction time. Moreover, the solid catalyst is easily be separated from the reaction mixture and recycled more than five times without any obvious decay in its activity. Powder X-ray diffraction (XRD), transmission electron microscope (TEM), UV-vis diffuse reflectance spectra (UV-DRS) and Raman analyses revealed identical structural integrity, particle size, absorption edge and valence state for the reused solid compared to the fresh solid catalyst.

Bye, fridends, I hope you can learn more about C7H5NO4, If you have any questions, you can browse other blog as well. See you lster.. Safety of 4-Nitrobenzoic acid

Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem