Rani, D; Bhargava, M; Agarwal, J in [Rani, Dixita; Bhargava, Meha; Agarwal, Jyoti] Panjab Univ, Dept Chem, Chandigarh 160014, India; [Rani, Dixita; Bhargava, Meha; Agarwal, Jyoti] Panjab Univ, Ctr Adv Studies, Chandigarh 160014, India published Asymmetric Michael Addition of Unactivated Ketones with beta-Nitrostyrenes Mediated by Bifunctional L-Prolinamide Organocatalysts in 2020.0, Cited 102.0. Name: 4-Nitrobenzoic acid. The Name is 4-Nitrobenzoic acid. Through research, I have a further understanding and discovery of 62-23-7.
The catalytic activity of two types of L-prolinamide organocatalysts was investigated for asymmetric Michael addition reaction of cyclic/acyclic ketones with beta-nitrostyrens. L-Prolinamides bearing amino groups on phenyl ring worked well, though their catalytic efficiency as well as selectivity was found to be dependent upon the position of amine group to the amide bond. Organocatalyst having -NH2 group ortho to amide bond provided the best results. Substrate scope was also studied by performing the reaction of various beta-nitrostyrenes with ketones to afford the corresponding Michael adducts in excellent yields with very high diastereoselectivities and enantioselectivities in almost all cases.
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