Recommanded Product: 62-23-7. Lee, JM; Bae, DY; Park, JY; Jo, HY; Lee, E; Rhee, YH; Park, J in [Lee, Jeong Min; Bae, Dae Young; Park, Jin Yong; Jo, Hwi Yul; Lee, Eunsung; Rhee, Young Ho; Park, Jaiwook] Pohang Univ Sci & Technol, Dept Chem, POSTECH, Pohang 37673, South Korea published Concurrent Formation of N-H Imines and Carbonyl Compounds by Ruthenium-Catalyzed C-C Bond Cleavage of beta-Hydroxy Azides in 2020, Cited 33. The Name is 4-Nitrobenzoic acid. Through research, I have a further understanding and discovery of 62-23-7.
A commercial cyclopentadienylrutenium dicarbonyl dimer ([CpRu(CO)(2)](2)) efficiently catalyzes the formation of N-H imines and carbonyl compounds simultaneously from beta-hydroxy azides via C-C bond cleavage under visible light. Density functional theory calculations for the cleavage reaction support the mechanism involving chelation of alkoxy azide species and liberation of nitrogen as the driving force. The synthetic utility of the reaction was demonstrated by a new amine synthesis promoted by chemoselective allylation of imine and synthesis of isoquinoline.
Recommanded Product: 62-23-7. Welcome to talk about 62-23-7, If you have any questions, you can contact Lee, JM; Bae, DY; Park, JY; Jo, HY; Lee, E; Rhee, YH; Park, J or send Email.
Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem