An article Visible-light-driven cyanoalkylation of quinoxalinones using cyclobutanone oxime esters as the radical precursors WOS:000480672900007 published article about C-H CYANOALKYLATION; IMINYL RADICALS; BOND FORMATION; QUINOXALIN-2(1H)-ONES; DERIVATIVES; INHIBITORS; ARYLATION; NITRILES; CLEAVAGE; STRATEGY in [Zhao, Bin; Kong, Xianqiang; Xu, Bo] Donghua Univ, Coll Chem Chem Engn & Biotechnol, Key Lab Sci & Technol Ecotext, Minist Educ, Shanghai 201620, Peoples R China in 2019.0, Cited 52.0. The Name is 4-Nitrobenzoic acid. Through research, I have a further understanding and discovery of 62-23-7. Product Details of 62-23-7
We have developed a versatile visible-light-driven cyanoalkylation of quinoxalinones under mild conditions. First, the cyanoalkyl radicals are generated from readily available cyclobutanone oxime esters under blue light irradiation. Then the generated radicals react with heterocycles such as quinoxalinones to give the final cyanoalkylation products. The protocol tolerates a wide range of functional groups. Our cyanoalkylation protocol does not need cyanide-based reagents and also does not need external oxidants. (C) 2019 Elsevier Ltd. All rights reserved.
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