Kumar, GR; Kumar, R; Rajesh, M; Sridhar, B; Reddy, MS in [Kumar, Gurram Ravi; Rajesh, Manda; Reddy, Maddi Sridhar] CSIR, OSPC Div, Indian Inst Chem Technol, Hyderabad 500007, Andhra Pradesh, India; [Kumar, Gurram Ravi; Kumar, Ravi; Rajesh, Manda; Reddy, Maddi Sridhar] Acad Sci & Innovat Res, New Delhi 110001, India; [Kumar, Ravi] CSIR, MPC Div, CDRI, Sitapur Rd, Lucknow 226031, Uttar Pradesh, India; [Sridhar, B.] CSIR, Analyt Div, IICT, Hyderabad 500007, Andhra Pradesh, India published Rh(III)-Catalyzed Intramolecular Oxidative Annulation of Propargyl Amino Phenyl Benzamides to Access Pyrido/ Isoquinolino Quinoxalinones in 2019, Cited 58. Recommanded Product: 4-Nitrobenzoic acid. The Name is 4-Nitrobenzoic acid. Through research, I have a further understanding and discovery of 62-23-7.
A rhodium catalyzed copper mediated double oxidative annulation of propargylamino phenyl benzamides is developed. A quick assembly of tri, tetra and penta cyclic pyrido/isoquinolo-quinoxilines are thus achieved from readily available linear substrates. The reaction is shown to be very general by accommodating a large variety of substrates in the transformation. A mechanism through an amide directed C-H bond activation followed by an intramolecular alkyne activation/annulation followed by an oxidation is postulated.
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Reference:
Phthalazine – Wikipedia,
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