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Measurement of the quantum yield of triplet formation and short triplet lifetimes by the transient grating technique

A transient grating method for measuring the quantum yield of triplet formation (Phiisc) and lifetimes of short-lived triplet states is proposed.The method is based on a measurement of time dependence of a thermal grating signal with a nanosecond pulsed laser and a cw probe laser.The validity of the method is demonstrated by determining Phiisc of a number of molecules whose Phiisc are known.Advantages and limitations of this method are discussed in detail.

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Reference£º
Phthalazine – Wikipedia,
Phthalazine | C8H6N442 – PubChem