Chemistry, like all the natural sciences, HPLC of Formula: C12H12Si, begins with the direct observation of nature¡ª in this case, of matter.775-12-2, Name is Diphenylsilane, SMILES is C1([SiH2]C2=CC=CC=C2)=CC=CC=C1, belongs to phthalazines compound. In a document, author is Wang, Xue-Mei, introduce the new discover.
Synthesis, structure and DFT calculation of a facial tris-cyclometalated phosphorescent iridium(III) complex containing substituted phthalazine ligands
The facial tris-cyclometalated iridium(III) complex fac-Ir(dmpopopz)(3) (dmpopopzH = 1-(2,6-dimethylphenyloxy)-4-(4-phenyloxyphenyl)-phthalazine) was synthesized from the reaction of iridium (III) chloride hydrate and ligand dmpopopzH in refluxing ethoxyethanol. The conformation of complex fac-Ir(dmpopopz)(3) is described on the basis of the H-1 NMR, C-13 NMR, FT-IR and mass spectroscopies, the crystal structure of fac-Ir(dmpopopz)(3) was determined by X-ray crystallography, and the theoretical calculation of complex fac-Ir(dmpopopz)(3) was also investigated by the DFT method. The absorption and emission spectral results exhibit that complex fac-[Ir(dmpopopz)(3)] may be used as a red-emitting phosphorescent material. Efficient OLEDs have been achieved using the complex fac-[Ir(dmpopopz)(3)] in the red-emitting region. (C) 2017 Published by Elsevier B.V.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 775-12-2. HPLC of Formula: C12H12Si.
Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem