Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. 81-48-1, Name is 1-Hydroxy-4-(p-tolylamino)anthracene-9,10-dione, molecular formula is , belongs to phthalazine compound. In a document, author is Hirakawa, Shota, Safety of 1-Hydroxy-4-(p-tolylamino)anthracene-9,10-dione.
A ruthenium complex containing a 1,9,10-anthyridine derivative, [Ru(L)(bpy)(2)](PF6)(2) ( [1] (PF6)(2); L = 1,13,14-triazadibenz[a,j]anthracene, bpy = 2,2′-bipyridyl), was synthesized. X-ray crystal structural analysis of [1](PF6)2 showed that L is coordinated to the Ru center as a bidentate ligand. When [1](PF6)(2) was dissolved in acetonitrile, a new complex incorporating one acetonitrile molecule, [Ru(L)(CH3CN)(bpy)(2)](PF6)(2) ([2] (PF6)(2)), was formed. X-ray crystallographic data revealed that, in [2](PF6)(2), L is coordinated to the Ru center in a monodentate fashion. The coordinated L in [2](PF6)(2) shows a unique haptotropic rearrangement in an acetonitrile solution.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 81-48-1 is helpful to your research. Safety of 1-Hydroxy-4-(p-tolylamino)anthracene-9,10-dione.
Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem