Safety of 4-Hydrazinylbenzoic acid, We’ll be discussing some of the latest developments in chemical about CAS: 619-67-0, Name is 4-Hydrazinylbenzoic acid, SMILES is O=C(O)C1=CC=C(NN)C=C1, belongs to phthalazine compound. In a article, author is Szavuly, Miklos, introduce new discover of the category.
A series of diiron(III) complexes of 1,3-bis(2′-arylimino)isoindoline, [(Fe(L)Cl)(2)O] and 1,4-di-(2′-aryl)aminophthalazine, [Fe-2(mu-OMe)(2)(H2L)Cl-4], including new structurally characterized ligands, 1,4-di-(4′-methyl-2′-thiazolyl)aminophthalazine and 1,4-di-(2′-benzthiazolyl)-aminophthalazine, have been characterized, and used as catalysts for the oxidation of para-substituted phenyl methyl sulfides and benzyl alcohols. Hammett correlations and kinetic isotope effect experiments support the involvement of electrophilic metal-based oxidants. In case of [(Fe(L-1,L-2)Cl)(2)O] catalysts, direct correlation has been found between the oxidative and catalase-like activity. (C) 2014 Elsevier B.V. All rights reserved.
If you are hungry for even more, make sure to check my other article about 619-67-0, Safety of 4-Hydrazinylbenzoic acid.
Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem