An article Ru(II)-Catalyzed Oxidative Olefination of Benzamides: Switchable Aza-Michael and Aza-Wacker Reaction for Synthesis of Isoindolinones WOS:000543669800008 published article about H BOND ACTIVATION; RUTHENIUM-CATALYZED CYCLIZATION; C-C; STEREOSELECTIVE-SYNTHESIS; FUNCTIONALIZATION; ALKENYLATIONS; ANNULATION in [Kumar, Manoj; Verma, Shalini; Verma, Akhilesh K.] Univ Delhi, Dept Chem, Delhi 110007, India in 2020.0, Cited 65.0. The Name is 4-Nitrobenzoic acid. Through research, I have a further understanding and discovery of 62-23-7. SDS of cas: 62-23-7
Selective tandem oxidative C-H olefination-azaMichael/aza-Wacker reaction of N-arylbenzamides is achieved by fine-tuning between base and additive to access valuable 3-oxoisoindolinyls and 3-oxoisoindolinylidenes, respectively. Careful optimization and control experiments provides a guiding principle in the design of a proposed catalytic cycle. The copper-iminium complex acting as a precursor for the binding of Ru catalyst was isolated and confirmed by X-ray diffraction. The versatility of this catalytic system has been demonstrated by the synthesis of biologically relevant molecules.
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Reference:
Phthalazine – Wikipedia,
,Phthalazine | C8H6N2 – PubChem